With nearly 500 comments on the thread on the Second Law of Thermodynamics there is obviously a need for people to discuss the basic greenhouse theory. Here’s a new thread on that theme.
So what is the Second Darn Law?
But there are variations
As with all these Laws of science there is no exact wording, because There Is No God Who Issues Science Decrees*. What we have are human efforts to best explain the world around us. Note that the two well known versions of the Second Law both contain the phrase “whose sole result”, meaning that heat transfer can certainly move from a colder to a warmer body if there is some other compensating movement where more heat is transferred from a hotter body to a colder one. Voila… whatever heat transfer goes from greenhouse gases to the Earth is more than countered by the heat moving from the Sun to Earth and on to space. Greenhouse gases can heat the Earth as long as the entropy of the whole system increases.
This is generating many comments, see below for an update!
Behind the scenes some skeptics are suggesting that CO2 can’t warm us because the atmosphere is colder than the planet, and it would break the 2nd Law of Thermodynamics (see Postma*, for example, p 6 – 7). I disagree. The 2nd Law of Thermodynamics applies to net flows of heat, not to each individual photon, and it does not prevent some heat flowing from a cooler body to a warm one.
Imagine three blocks of metal side by side. They are 11°C, 10°C, and 9°C. Think about what happens to the photons coming off the atoms in the middle of the medium temperature block between the other two. If heat never flows from cooler blocks to warmer blocks, all those photons have to go “right“, and not ever go “left”, because they “know” that way is towards a cooler block? (How would they?!)
The photons go both ways (actually every way, in 3D). There are more coming from the 11°C block to the 10°C block, sure, but the the 10°C block is sending ‘em back to the 11°C block too. So heat is flowing from cold to hot. It happens [...]